A 4 L sample of gas at 30 degrees celcius and 1 atm is changed to 0 degrees celcius and 800torr. What is its new volume?

The correct presentation is;

6 CO2 (g) + H2O (l)  → C6H12O6 (aq) + 6 O2 (g)  ΔH = 801 kJ/mole

A chemical reaction known as an endothermic reaction draws energy from its surroundings, causing the temperature of those surroundings to drop. This indicates that energy must be added to the system in order for the reaction to take place because the reactants of the reaction have a lower enthalpy (energy content) than the products.

Because the absorbed energy during an endothermic reaction is typically in the form of heat, the reaction feels cold to the touch.

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Extraction is a useful technique for separating and purifying mixtures of compounds based on differences in their physical properties and reaction types.

The physical property used in extraction is the solubility of a compound in a particular solvent. If a compound is more soluble in one solvent than another, it can be selectively extracted and separated from the mixture.

For example, if a mixture contains both water-soluble and oil-soluble compounds, the mixture can be extracted with water to separate the water-soluble compounds, and then extracted with an organic solvent to separate the oil-soluble compounds.

The reaction type used in extraction is often acid-base chemistry. If a mixture contains both acidic and basic compounds, they can be selectively extracted by adjusting the pH of the solvent.

For example, if a mixture contains both an acidic carboxylic acid and a basic amine, the mixture can be extracted with a basic solvent to selectively extract the amine, and then extracted with an acidic solvent to selectively extract the carboxylic acid.

Overall, extraction is a powerful technique for separating and purifying mixtures of compounds, and its effectiveness depends on the physical properties and reaction types of the compounds in the mixture.

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Using an ice bath to cool the solution is most likely to reduce the concentration of sodium chloride in the solution. Option D is correct.

When a solution is cooled, the solubility of most solids decreases. As a result, some of the sodium chloride may precipitate out of the solution, reducing the concentration of the solute. The other options listed would not reduce the concentration of sodium chloride in the solution.

Heating the solution on a hot plate could potentially increase the solubility of sodium chloride and lead to more dissolving, whereas adding more sodium chloride would only increase the concentration. Removing some solution with a pipette would not change the concentration, as the amount of solute would remain the same in the remaining solution. Hence Option D is correct.

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D. A mountain range with folded layers of rock.

Intense compression can cause the rock layers to fold, creating a mountain range. This type of feature forms suddenly in the geological timescale, as a result of tectonic activity, and is known as a fold mountain.

The intense pressure causes the rock layers to buckle and deform, resulting in folds, faults, and other features. The Appalachian Mountains and the Rocky Mountains are examples of fold mountains in the United States.

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Answer:

yes

Explanation:

yes, avalanches a big part in the shaping of the earths surface.

Yes, avalanches can play a significant role in shaping the Earth's surface, particularly in mountainous areas.

The movements of snow, ice, and debris down a slope known as avalanches can significantly impact the Earth's surface, especially in mountainous regions. These natural occurrences can cause various landscape changes, erosion, and deposition.

Answer: 134g NH3

Explanation:

Diatomic Hydrogen has a mass of 2.016g/mol

to find how many moles of H2 we have divide how much we have by the molar mass.

23.5g/2.016= 11.66 moles

the ratio between H2 moles and NH3 moles is 3 moles of H2 produce 2 moles of NH3 so we multiply using a 2/3 ratio to find how many moles of NH3 we have

11.66mol H2 x (2molNH3/3molH2) = 7.77 moles NH3

now we multiply the number of moles of NH3 by the molar mass of NH3 (17.3g/mol) to find how many grams of NH3 we have.

7.77 x 17.3g = 134.4g NH3 or using 3 sig figs 134g NH3

Based on the lab analysis, we used potassium carbonate and potassium sulfate to determine whether our unknown solution was strontium nitrate or magnesium nitrate.

When we mixed the unknown solution with potassium carbonate, we observed a white precipitate forming, indicating that the unknown solution contained a carbonate ion. When we mixed the unknown solution with potassium sulfate, we observed no change, indicating that the unknown solution did not contain a sulfate ion.

Using the solubility rules, we know that strontium carbonate is insoluble, while magnesium carbonate is soluble. Therefore, since we observed a white precipitate forming, we can conclude that our unknown solution was strontium nitrate.

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The pH of the solution prepared by mixing 30.00 ml of 0.10 M CH3CO2H with 30.00 ml of 0.030 M CH3CO2K is 4.22.

To determine the pH of the solution prepared by mixing 30.00 ml of 0.10 M CH3CO2H with 30.00 ml of 0.030 M CH3CO2K, we first need to calculate the concentration of CH3CO2H and CH3CO2K in the final solution.

Since the volumes are additive, the total volume of the solution is 60.00 ml. The moles of CH3CO2H present in the solution can be calculated as follows:

Moles of CH3CO2H = concentration (M) x volume (L)
Moles of CH3CO2H = 0.10 M x 0.030 L
Moles of CH3CO2H = 0.003 moles

Similarly, the moles of CH3CO2K present in the solution can be calculated as:

Moles of CH3CO2K = concentration (M) x volume (L)
Moles of CH3CO2K = 0.030 M x 0.030 L
Moles of CH3CO2K = 0.0009 moles

Since CH3CO2H and CH3CO2K react with each other to form a buffer solution, we can use the Henderson-Hasselbalch equation to calculate the pH of the solution:

pH = pKa + log ([CH3CO2K] / [CH3CO2H])

where pKa is the dissociation constant of CH3CO2H (1.8 x 10–5).

Substituting the values of moles of CH3CO2H and CH3CO2K, we get:

pH = pKa + log ([0.0009] / [0.003])
pH = 4.74 + log (0.3)
pH = 4.74 - 0.52
pH = 4.22

Therefore, the pH of the solution prepared by mixing 30.00 ml of 0.10 M CH3CO2H with 30.00 ml of 0.030 M CH3CO2K is 4.22.

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The pH of a 6.3 x [tex]10^{-8[/tex]M solution of H₃O+ is approximately 7.20.

A 0.25 M solution of H₃O+ is not a strong acid, since it is not a single acid that completely dissociates in water.

A 6.3 x [tex]10^{-8[/tex] M solution of H₃O+  is not a strong acid, since it is a very weak acid with a very low concentration of H₃O+ ions.

The pH of a 0.25 M solution of H₃O+ can be calculated using the formula:

pH = -log[H₃O+]

where [H₃O+] is the concentration of H₃O+ ions in moles per liter (M).

In this case, [H3O+] = 0.25 M,

pH = -log(0.25) = 0.602

Therefore, the pH of a 0.25 M solution of H₃O+ is approximately 0.602.

The pH of a 6.3 x [tex]10^{-8[/tex] M solution of H₃O+ can be calculated using the same formula:

pH = -log[H₃O+]

In this case, [H₃O+] = 6.3 x [tex]10^{-8[/tex]M, so we have:

pH = -log(6.3 x [tex]10^{-8[/tex]) = 7.20

Therefore, the pH of a 6.3 x [tex]10^{-8[/tex] M solution of H₃O+ is approximately 7.20.

There is no information given for question 3.

A strong acid is an acid that completely dissociates in water to produce H₃O+  ions. The most common example of a strong acid is hydrochloric acid (HCl).

Looking at the given solutions:

A 0.25 M solution of H₃O+  is not a strong acid, since it is not a single acid that completely dissociates in water.

A 6.3 x [tex]10^{-8[/tex] M solution of H₃O+  is not a strong acid, since it is a very weak acid with a very low concentration of H₃O+  ions.

Therefore, neither of the given solutions is a strong acid.

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If cost is a significant constraint for Itea city in choosing a water purification method for their water supply, then the fact that ion exchange systems are more expensive because of the use of filters that need replacement would be important to consider.

While reverse osmosis systems are also more expensive, it is primarily due to the chlorine treatments, which may not be a significant factor for the city. Therefore, ion exchange systems may not be a cost-effective option in the long run due to the ongoing expenses of replacing filters.

This information can help inform the city's decision-making process and ensure that they choose a water purification method that meets their needs while also being financially feasible.

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Answer:

yes acid can nuetralize bases

Answer:

Yes!

Explanation:

Strong Acids neutralize Strong bases.

When they react, water is formed. Whatever ions are left over, they become salt.

There must be an equal moles of strong acid and strong base.

The molarity of the sugar solution is 0.5988 M (mol/L).

To calculate the molarity of a solution, we need to know the number of moles of solute (the substance being dissolved) and the volume of the solution in liters.

First, we need to determine the number of moles of sugar (C12H22O11) in the given mass of 102.6 grams:

The molar mass of C12H22O11 can be calculated as follows:

12(12.01 g/mol) + 22(1.01 g/mol) + 11(16.00 g/mol) = 342.3 g/mol

The number of moles of C12H22O11 in 102.6 grams can be calculated as:

102.6 g / 342.3 g/mol = 0.2994 mol

Next, we need to convert the volume of the solution from milliliters to liters:

mL = 0.5 L

Now we can calculate the molarity (M) of the solution:

M = moles of solute/liters of solution

M = 0.2994 mol / 0.5 L

M = 0.5988 M

Therefore, the molarity of the sugar solution is 0.5988 M (mol/L).

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The substrates that will react are CH₃CH₂CH₂Br and CH₃CH₂CH₂CH₂Br  and (CH₃)₃CNH₂ and CH₃CH₂OH will not react with naome in an sn2 reaction to form an appreciable amount of product.

Based on the Sn2 reaction mechanism, substrates with good leaving groups and low steric hindrance are more likely to react with nucleophiles like NaOMe.

Therefore, the substrates CH₃CH₂Br, (CH₃)₂CHBr, CH₃CH₂I, and (CH₃)₃CBr are expected to react with NaOMe to form appreciable amounts of product. On the other hand, substrates with poor leaving groups or high steric hindrance are less likely to undergo Sn2 reactions.

Therefore, the substrates (CH₃)₃CNH₂ and CH₃CH₂OH are not expected to react with NaOMe to form appreciable amounts of product. Finally, CH₃CH₂CH₂Br and CH₃CH₂CH₂CH₂Br may react with NaOMe, but to a lesser extent due to their higher steric hindrance.

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Complete question :

Determine which of the substrates will and will not react with NaOMe in an Sy2 reaction to form an appreciable amount of product. Substrate will react Substrate will NOT react Answer Bank CH,CH.CH,BE (CH),CBE (CH), CHRE CH, CH,CH,NH, (CH),CCH,BE CH,CH.CH, OH

9. Using the combined gas law, the volume of the gas at STP can be calculated as 112.2 L. This equation takes into account the initial pressure, temperature, and volume, as well as the new pressure and temperature at STP.

10. Applying Boyle's law, the new volume of the air inside the submarine would be approximately 87,873.2 L. This is calculated by multiplying the initial volume and pressure, and dividing by the new pressure.

11. Using the combined gas law, the new volume of the balloon can be calculated as 0.98 L. This equation takes into account the initial temperature, volume, and pressure, as well as the new temperature.

12. Using Boyle's law, the new pressure of the gas can be calculated as 3.25 atm. This equation takes into account the initial pressure and volume, as well as the new volume.

13. Using Charles' law, the new volume of the person's lungs can be calculated as 3.8 L. This equation takes into account the initial lung capacity and temperature, as well as the new temperature.

It is highly unlikely that a person would actually explode from anger, as the body has mechanisms in place to regulate pressure and prevent such an event.

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In general, a system tends to favor a reaction that results in an increase in entropy, which is a measure of the number of possible arrangements of the system's particles. The answer is A) lower energy and higher entropy.

This is due to the fact that the increase in the number of particles in the system or the increase in the number of ways the particles can be arranged leads to an increase in entropy. On the other hand, a system also tends to favor a reaction that results in a decrease in energy, which is a measure of the system's ability to do work.

Therefore, when a system undergoes a reaction that decreases its energy while increasing its entropy, it is moving towards a more stable and disordered state.

This is because a lower energy state means that the system is releasing energy, while a higher entropy state means that the system is becoming more disordered and spread out. This tendency towards lower energy and higher entropy is known as the second law of thermodynamics, which governs the behavior of all physical systems.

The answer is A) lower energy and higher entropy.

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Both 1.0 mol of calcium (Ca) and 1.0 mol of magnesium (Mg) contain the same number of atoms (Avogadro's number, 6.022 x 10²³ atoms), but they differ in mass and chemical properties.

In order to compare 1.0 mol Ca and 1.0 mol Mg, we must first understand the concept of a mole. A mole is a unit of measurement that represents 6.022 x 10²³ particles (atoms, molecules, ions, etc.). This number, known as Avogadro's number, allows us to compare amounts of different substances.

Although 1.0 mol Ca and 1.0 mol Mg both contain the same number of atoms, their masses are different. The molar mass of Ca is 40.08 g/mol, while the molar mass of Mg is 24.31 g/mol.

Therefore, 1.0 mol Ca has a mass of 40.08 g, and 1.0 mol Mg has a mass of 24.31 g. Additionally, Ca and Mg are both alkaline earth metals but possess different chemical properties, such as reactivity and electron configurations.

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I agree with the student's claim that a 4-gram paintball fired from a paintball gun at 90 m/s could have about the same kinetic energy as a 1-gram bb pellet fired from a bb gun at 180 m/s.

To answer this question, we need to compare the kinetic energy of the paintball and the bb pellet. The formula for kinetic energy is 1/2mv^2, where m is the mass of the object and v is its velocity.

For the paintball, with a mass of 4 grams and a velocity of 90 m/s, the kinetic energy is:

1/2 * 0.004 kg * (90 m/s)^2 = 18.18 joules

For the bb pellet, with a mass of 1 gram and a velocity of 180 m/s, the kinetic energy is:

1/2 * 0.001 kg * (180 m/s)^2 = 16.2 joules

So, the student's claim is actually true - the 4-gram paintball fired at 90 m/s has slightly more kinetic energy than the 1-gram bb pellet fired at 180 m/s. However, it's worth noting that the two projectiles have different sizes and shapes, and would behave differently upon impact.

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The pH of the resulting mixture is closest to 2.48, which is in the acidic range.

The reaction between HCl and NaOH produces water and NaCl:

HCl + NaOH → NaCl + H₂O

Moles of HCl = 1.0 mol/L × 0.5 L = 0.5 moles

Moles of NaOH = 2.0 mol/L × 0.2 L = 0.4 moles

NaOH is a limiting factor since it has fewer moles than HCl.

Excess H⁺ ions = 0.5 moles - 0.4 moles = 0.1 moles

Excess OH⁻ ions = 0.4 moles

To calculate the pH of the solution, we need to know the concentration of excess H⁺ or OH⁻ ions. Since we know the amount of excess H⁺ and OH⁻ ions, we can calculate their concentrations using the volume of the solution.

The total volume of the solution is 200 mL + 500 mL = 0.7 L

The concentration of excess H+ ions is:

[H⁺] = 0.1 moles ÷ 0.7 L = 0.143 mol/L

The concentration of excess OH- ions is:

[OH⁻] = 0.4 moles ÷ 0.7 L = 0.571 mol/L

Since the concentration of OH⁻ ions is higher than the concentration of H⁺ ions, the solution is basic. The pH can be calculated using the equation:

pH = 14 - pOH

pOH = -log[OH⁻]

pOH = -log(0.571)

pOH = 0.242

Thus, pH = 14 - 0.242 = 13.76

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ans.

blank 1 = 1

blank 2 = 5

blank 3 = 3

blank 4 = 4

To solve this problem, we first need to write and balance the chemical equation for the reaction between strontium chloride and sulfuric acid:

SrCl2 + H2SO4 → SrSO4 + 2HCl

According to the balanced chemical equation, one mole of strontium chloride reacts with one mole of sulfuric acid to produce one mole of strontium sulfate and two moles of hydrochloric acid.

Next, we need to calculate the number of moles of sulfuric acid we have:

moles of H2SO4 = mass of H2SO4 / molar mass of H2SO4

moles of H2SO4 = 300.0 g / 98.08 g/mol

moles of H2SO4 = 3.057 mol

Finally, we can use the stoichiometry of the balanced chemical equation to determine the number of moles of strontium chloride that will react with 3.057 moles of sulfuric acid:

moles of SrCl2 = moles of H2SO4

moles of SrCl2 = 3.057 mol

Now we can calculate the mass of strontium chloride using its molar mass:

mass of SrCl2 = moles of SrCl2 x molar mass of SrCl2

mass of SrCl2 = 3.057 mol x 158.53 g/mol

mass of SrCl2 = 485.1 g

Therefore, 485.1 grams of strontium chloride will react with 300.0 grams of sulfuric acid.

Explanation:

To solve this problem, we use stoichiometry, which is a method that relates the amount of reactants and products in a chemical reaction based on their balanced chemical equation. In this case, we first write and balance the chemical equation for the reaction between strontium chloride and sulfuric acid. Then, we calculate the number of moles of sulfuric acid given its mass and molar mass. Next, we use the stoichiometry of the balanced chemical equation to determine the number of ontium chloride that will react with the given amount of sulfuric acid. Finally, we calculate the mass of strontium chloride using its molar mass and the calculated number of moles. By following these steps, we can determine the mass of strontium chloride that will react with 300.0 grams of sulfuric acid.

The phases of the moon are a result of the relative positions of the sun, the earth, and the moon. Option A is correct.

As the moon orbits around the earth, the amount of sunlight that reflects off its surface changes, causing the different phases. When the moon is between the sun and the earth, we see a new moon. When the earth is between the sun and the moon, we see a full moon. When the moon is at a right angle to the earth and the sun, we see a quarter moon.

The size of the moon has no effect on the phases, as it appears to be the same size regardless of the phase. The number of craters on the moon is also unrelated to the phases. Therefore, Student A's explanation is the most accurate and supported by scientific evidence.  Option A is correct.

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The ball would experience a net force of 0 N and would not move in either direction.

When the boy kicks the ball with a force of 40 N, he applies a force in one direction. At the same moment, a gust of wind blows in the opposite direction of the kick with a force of 40 N. These two forces act in opposite directions, and therefore cancel each other out.

According to Newton's first law of motion, an object at rest will remain at rest, and an object in motion will continue in motion in a straight line at a constant speed, unless acted upon by a net external force. In this case, the net force on the ball is 0 N, which means that the ball will not move in either direction.

This scenario highlights the importance of understanding net forces when analyzing the motion of objects. In the absence of a net force, the ball will not accelerate, and its velocity will remain constant.

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Robert Millikan later determined electron's charge in his "oil drop" experiments.

J.J. Thomson conducted experiments in the late 19th century where he used an electric field to deflect a beam of particles, known as a "cathode ray." These cathode rays were generated by applying a high voltage to a partially evacuated glass tube. Thomson observed that the beam was deflected towards the positive electrode, suggesting that the particles in the cathode ray had a negative charge. This led him to the discovery of the first subatomic particle, the electron.

Robert Millikan later conducted experiments to determine the charge of the electron. His famous "oil drop" experiments involved suspending tiny droplets of oil in an electric field and measuring the force required to keep them stationary. By measuring the charge on the oil droplets and the electric field strength, he was able to calculate the charge of the individual electrons that were present in the oil droplets. The discovery of the electron and its properties paved the way for future developments in particle physics and quantum mechanics. Today, we understand that atoms are made up of a nucleus composed of protons and neutrons, surrounded by electrons that orbit the nucleus in energy levels.

The conclusion is J. J. Thomson discovered the first subatomic particle, the electron, by deflecting a "cathode ray" beam with an electric field. Robert Millikan later determined that particle's charge in his "oil drop" experiments. The discovery of the electron was a crucial step in our understanding of the nature of matter and the structure of the universe.

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To answer this question, we need to use the equation for molarity, which is:
Molarity = moles of solute / volume of solution in liters
We can rearrange this equation to solve for the volume of solution:

Volume of solution = moles of solute / molarity
First, we need to calculate the number of moles of HCl in 32.0 g. The molar mass of HCl is 36.5 g/mol, so:
32.0 g / 36.5 g/mol = 0.8767 mol HCl

Next, we need to calculate the volume of solution needed to make a 4.80 m solution. Using the equation above:
Volume of solution = 0.8767 mol / 4.80 mol/L = 0.1826 L or 182.6 mL
Finally, we need to calculate how much water needs to be added. We started with 32.0 g of HCl and added water to make a total volume of 182.6 mL. The volume of water added is therefore:

Volume of water added = 182.6 mL - 32.0 g / 1 g/mL = 150.6 mL
Converting to liters:
Volume of water added = 150.6 mL / 1000 mL/L = 0.1506 L

Therefore, the answer is 0.18 L of water should be added to 32.0 g of HCl to make a 4.80 m solution.

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The dry gas would occupy 1.46 L at standard conditions.

When gas is collected over water, the vapor pressure of the water affects the total pressure measured. To account for this, we need to use Dalton's law of partial pressure, which states that the total pressure of a gas mixture is the sum of the partial pressures of each gas component.

First, we need to calculate the partial pressure of the collected gas. We can do this by subtracting the vapor pressure of water at 20 degrees Celsius (17.5 mm Hg) from the total pressure measured:

Partial pressure of gas = total pressure - vapor pressure of water
Partial pressure of gas = 622.0 mm Hg - 17.5 mm Hg
Partial pressure of gas = 604.5 mm Hg

Next, we can use the ideal gas law (PV = nRT) to calculate the volume of the dry gas at standard conditions (0 degrees Celsius and 1 atm):

PV = nRT
V = nRT/P

where P is the partial pressure of the gas (604.5 mm Hg converted to atm), n is the number of moles of gas (which we can calculate using the volume of the collected gas and the known molar volume of a gas at STP), R is the gas constant, and T is the temperature in Kelvin (273 K).

V = (40 L)(0.0821 L·atm/mol·K)(293 K)/(0.793 atm)
V = 1.46 L

Therefore, the dry gas would occupy 1.46 L at standard conditions.

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To produce 235 mL of a 1.77 M H₂SO₄ solution from an 18.0 M H₂SO₄ solution, you would need 27.54 mL of the concentrated solution.

To find this, we can use the dilution formula: M₁V₁ = M₂V₂. Here, M₁ is the initial concentration (18.0 M), V₁ is the volume required, M₂ is the final concentration (1.77 M), and V₂ is the final volume (235 mL).

1. Rearrange the formula to solve for V₁: V₁ = (M₂V₂) / M₁
2. Plug in the given values: V₁ = (1.77 M × 235 mL) / 18.0 M
3. Calculate the result: V₁ = 27.54 mL

Therefore, you would need 27.54 mL of the 18.0 M H₂SO₄ solution to produce 235 mL of a 1.77 M H₂SO₄ solution.

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The student's task is to determine the density of the four mystery liquids using the mass and volume measurements.

Density is a physical property that describes the amount of mass per unit volume.

The formula for density is density = mass/volume. Once the density of each liquid is determined, the student can compare it to known densities of different substances to identify the liquid.

This information can be useful in various fields such as chemistry, pharmacology, and environmental science.

The student may also use this data to calculate other properties of the liquids such as viscosity, surface tension, and boiling point. Overall, measuring mass and volume is a fundamental method in scientific research and analysis.

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If we had a 32-gram sample of C-14 today, there would be 4 grams of C-14 remaining in 10,470 years.

The half-life of C-14 is 5370 years, which means that in 5370 years, half of the original sample of C-14 would decay. After another 5370 years, half of what remains would decay, and so on.

This can be modeled by the equation:

[tex]N = N_0(1/2)^{(t/T)[/tex]

Where:

N is the amount of C-14 remaining after time t

N₀ is the initial amount of C-14

T is the half-life of C-14

Using the given information, we can substitute N₀ = 32 g, T = 5370 years, and t = 10,470 years into the equation to find N:

[tex]N = 32 g \cdot (1/2)^{(\frac{10,470 years}{5370 years})[/tex]

N = 4 g

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the concentration of barium ion when precipitation begins is approximately 3x =


3(7.93 × 10^-9 M) = 2.38 × 10^-8 M.

Hence, the concentration of barium ion when precipitation begins is approximately 2.38 × 10^-8 M.

To determine which substance precipitates first and the concentration of barium ion when precipitation begins, we need to consider the solubility product (Ksp) of the possible precipitation reactions.

The possible precipitation reactions are:

Ba(CrO4)2(s) ⇌ Ba2+(aq) + CrO42-(aq)   Ksp1 = [Ba2+][CrO42-]^2

Ba3(PO4)2(s) ⇌ 3Ba2+(aq) + 2PO43-(aq)   Ksp2 = [Ba2+]^3[PO43-]^2

The substance that precipitates first is the one with the lower solubility product (Ksp) value. To determine the Ksp values, we need to look up the relevant values of the solubility products.

From the solubility product table, we find:

- Ksp1 for Ba(CrO4)2 is 1.17 × 10^-10
- Ksp2 for Ba3(PO4)2 is 1.34 × 10^-23

Comparing the Ksp values, we see that Ksp1 is much larger than Ksp2, indicating that Ba(CrO4)2 is more soluble than Ba3(PO4)2.

Therefore, the precipitate that forms first is Ba3(PO4)2(s).

To determine the concentration of barium ion when precipitation begins, we can use the Ksp2 expression and assume that x mol/L of Ba3(PO4)2(s) dissolves, forming 3x mol/L of Ba2+ and 2x mol/L of PO43-. Since the initial concentration of ammonium phosphate is 1.04×10^-2 M, which is much less than the initial concentration of potassium chromate (1.49×10^-2 M), we can assume that all of the phosphate ions come from the ammonium phosphate and ignore the small contribution from the autoionization of water.

Using the Ksp2 expression and the concentrations of PO43- and Ba2+, we get:

Ksp2 = [Ba2+]^3[PO43-]^2
1.34 × 10^-23 = (3x)^3(2x)^2

Solving for x, we get:

x = 7.93 × 10^-9 M

Therefore, the concentration of barium ion when precipitation begins is approximately 3x =

3(7.93 × 10^-9 M) = 2.38 × 10^-8 M.

Hence, the concentration of barium ion when precipitation begins is approximately 2.38 × 10^-8 M.
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a. To plot the k emission intensity vs. the concentration of k, we can use the given data for the standard solutions of NaCl.

The concentration of K can be expressed in parts per million (ppm) and the corresponding intensity values can be plotted on a graph. Using regression analysis, we can determine the linearity of the data. The resulting graph should show a linear relationship between concentration and intensity.

b. To plot the ratio of the k intensity to the li intensity vs. the concentration of k, we can divide the intensity of K by the intensity of Li for each standard solution and the unknown.

The resulting values can be plotted against the concentration of K. The linearity of this graph can also be determined using regression analysis. The internal standard improves linearity because it helps to correct for any variations in sample handling and instrument response, resulting in more accurate and precise measurements.

c. To calculate the concentration of K in the unknown, we can use the ratio of the intensity of K to Li and the calibration curve obtained from the standard solutions.

From the graph in part (b), we can determine the concentration of K in the unknown by finding its corresponding value on the x-axis. Alternatively, we can use the regression equation obtained from part (a) to calculate the concentration of K in the unknown based on its measured intensity.

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