A 1-liter solution contains 0.494 M hydrofluoric acid and 0.371 M potassium fluoride. Addition of 0.408 moles of hydrochloric acid will: (Assume that the volume does not change upon the addition of hydrochloric acid.)
a. Raise the pH slightly
b. Lower the pH slightly
c. Raise the pH by several units
d. Lower the pH by several units
e. Not change the pH
f. Exceed the buffer capacity

Answers

Answer 1

Answer:

Option f: an addition of HCl will exceed the buffer capacity. The option d is also correct since it is a consequence of the option f.

Explanation:

The pH of the buffer solution before the addition of HCl is:

[tex]pH = pKa + log(\frac{[KF]}{[HF]})[/tex]

[tex]pH = -log(6.8 \cdot 10^{-4}) + log(\frac{0.371}{0.494}) = 3.04[/tex]  

The hydrochloric acid added will react with the potassium fluoride as follows:

H₃O⁺(aq)  +  F⁻(aq) ⇄   HF(aq) + H₂O(l)

The number of moles (η) of potassium fluoride (KF) and the HF before the addition of HCl is:

[tex] \eta_{KF}_{i} = C_{KF}*V = 0.371 M*1 L = 0.371 mol [/tex]

[tex] \eta_{HF}_{i} = C_{HF}*V = 0.494 M*1 L = 0.494 moles [/tex]

The number of moles of the HCl added is 0.408 moles. Since the number of moles of HCl is bigger thant the number of moles of KF, the moles of HCl that remains after the reaction is:

[tex] \eta_{HCl} = \eta_{HCl} - \eta_{KF}_{i} = 0.408 moles - 0.371 moles = 0.037 moles [/tex]  

Hence, the KF is totally consumed after the reaction with HCl and thus, exceding the buffer capacity.  

We can calculate the pH after the addition of HCl:

HF(aq) + H₂O(l) ⇄ F⁻(aq) + H₃O⁺(aq)    (1)

The number of moles of HF after the reaction of KF with HCl is:

[tex] \eta_{HF} = 0.494 moles + (0.408 moles - 0.371 moles) = 0.531 moles [/tex]

And the concentration of HF after the reaction of KF with HCl is is:

[tex] C_{HF} = \frac{\eta_{HF}}{V} = \frac{0.531 moles}{1 L} = 0.531 moles/L [/tex]

Now, from the equilibrium of equation (1) we have:

[tex] Ka = \frac{[H_{3}O^{+}][F^{-}]}{[HF]} [/tex]

[tex] Ka = \frac{x^{2}}{0.531 - x} [/tex]  (2)

By solving equation (2) for x we have:

x = 0.0187

Finally, the pH after the addition of HCl is:

[tex] pH = -log (H_{3}O^{+}) = -log (0.0187) = 1.73 [/tex]

Therefore, the addition of HCl will exceed the buffer capacity and thus, lower the pH by several units. The correct option is f: an addition of HCl will exceed the buffer capacity. The option d is also correct since it is a consequence of the option f.

I hope it helps you!


Related Questions

Iodine pentafluoride gas reacts with iodine fluoride gas producing iodine heptafluoride gas and iodine gas. What is the maximum number of grams of iodine gas that can be produced from a reaction of 10.0 g of iodine pentafluoride with 11.20 L of iodine fluoride gas at STP

Answers

Answer:

63.45g of I₂ can be produced

Explanation:

IF₅ reacts with IF to produce IF₇ and I₂. The reaction is:

IF₅ + 2 IF → IF₇ + I₂

Moles of 10.0g of IF₅ (221.89g/mol):

10.0g IF₅ × (1mol / 221.89g) = 0.0451 moles of IF₅

Using PV / RT = n, it is possible to find moles of 11.20L of IF, thus:

1atm×11.20L / 0.082atmL/molK × 273K = 0.500 moles of IF.

At STP, pressure is 1atm, temperature is 273K and gas constant R is 0.082atmL/molK

For a complete reaction of IF₅ you need:

0.0451 moles of IF₅ × (2 moles IF / 1 mole IF₅) = 0.902 moles of IF. As you have just 0.500 moles of IF, the IF is the limiting reactant.

2 moles of IF produce 1 mole of I₂. 0.500 moles of IF produce:

0.500mol IF ₓ ( 1 mol I₂ / 2 mol IF) = 0.250 mol I₂

As molar mass of I₂ is 253.81g/mol, mass of 0.250 mol I₂ are:

0.250mol I₂ ₓ (253.81g / mol) =

63.45g of I₂ can be produced

To lift fingerprints from a crime scene, a solution of silver nitrate is sprayed on a surface to react with the sodium chloride left behind by perspiration. What is the molarity of a silver nitrate solution if 42.8 mL of it reacts with excess sodium chloride to produce 0.148g of precipitate according to the following reaction?
AgNO3(aq)+NaCl(aq) --> AgCl(s)+NaNO3(aq)
A) 2.41 x 10^-2 M
B) 0.0229 M
C) 6.66 x 10^-2 M
D) 3.2 x 10^-3 M
E) 2.29 x 10^2 M

Answers

Answer:

A) 2.41 * 10^-2 M

Explanation:

Here we go from grams of percipitate to moles of Silver nitrate because we already know NaCl is excess so we don't care about that.

[tex]0.148gAgCl * \frac{1mol AgCl}{143.32 g AgCl} * \frac{1 mol AgNO3}{1 mol AgCl}\\ = 0.00103 mol AgNO3[/tex]

Now that we have moles we know molarity is moles/litres so we just plug it in:

Molarity = mol/litres = 0.00103/0.0428 L = 0.0241 M or 2.41 * 10^-2 M

Aqueous hydrobromic acid reacts with solid sodium hydroxide to produce aqueous sodium bromide and liquid water . If of water is produced from the reaction of of hydrobromic acid and of sodium hydroxide, calculate the percent yield of water. Round your answer to significant figures.

Answers

Answer:

See explanation below

Explanation:

You are missing certain data. I found one, in the attached picture. All you have to do is replace your data in this procedure to get an accurate answer.

According to the picture attached, we have 2.4 g of HBr and 1.9 g of NaOH. This mix produces 0.411 g of water. To get the %yield of water, we first need to see how many theorical grams of water are formed. With this we can calculate the %yield.

The overall reaction is:

HBr + NaOH --------> NaBr + H₂O

We have a mole ratio of 1:1 so, let's see which is the limiting reactant between the acid and the base, using the reported molar mass for each (MM HBr = 80.9119 g/mol; MM NaOH = 39.997 g/mol)

moles HBr = 2.4 / 80.9119 = 0.02966 moles

moles NaOH = 1.9 / 39.997 = 0.0475 moles

So, we can clearly see that the moles of NaOH are in excess, so the HBr is the limiting reactant.

As we have a mole ratio of 1:1 with each compound here, and that the HBr is the limiting reactant we can say that:

moles HBr = moles H₂O = 0.02966 moles of water

Now, using the molar mass of water, let's calculate the theorical yield of water: (MM water = 18.01528 g/mol

m H₂O = 0.02966 * 18.01528 = 0.534 g

We have the theorical yield, let's calculate the % yield:

% = 0.411 / 0.534 * 100

% = 76.92%

According to Rutherford's nuclear theory, the core of an atom (nucleus) contains most of the_____of an atom and is______, so the majority of the mass of a fluorine atom cannot be due to its nine electrons. According to Rutherford's nuclear theory, most of the volume of an atom is empty space, so the volume of a hydrogen atom cannot be mostly due to the proton. According to Rutherford's nuclear theory, the number of negatively charged particles outside the nucleus is_____the number of positively charged particles within the nucleus, so a nitrogen atom has 7 protons and 7 electrons, while a phosphorous atom cannot have 15 protons and 150 electrons.

Answers

Answer:

matter, dense, equal

Explanation:

According to Rutherford's nuclear theory, the core of an atom (nucleus) contains most of the matter of an atom and is dense, so the majority of the mass of a fluorine atom cannot be due to its nine electrons. According to Rutherford's nuclear theory, most of the volume of an atom is empty space, so the volume of a hydrogen atom cannot be mostly due to the proton. According to Rutherford's nuclear theory, the number of negatively charged particles outside the nucleus is equal the number of positively charged particles within the nucleus, so a nitrogen atom has 7 protons and 7 electrons, while a phosphorous atom cannot have 15 protons and 150 electrons.

If 0.089 grams of KI is dissolved in 500g of H2O, what is the concentration of the resulting solution in parts per million?

Answers

Answer:

The concentration of the resulting solution in parts per million is 177.97

Explanation:

Parts per million (ppm), is a unit of measure for concentration that refers to the number of units of the substance per million units of the set.

The concentration in parts per million expressed in mass / mass is calculated by dividing the mass of the solute (ms) by the mass of the solution (md, sum of the mass of the solute and the mass of the solvent), both expressed in the same unit and multiplied by 10⁶ (1 million).

[tex]ppm=\frac{ms}{md} *10^{6}[/tex]

So, being:

ms: 0.089 grams of KImd: 0.089 grams of KI + 500 grams of H₂O= 500.089 grams

Replacing:

[tex]ppm=\frac{0.089 grams}{500.089 grams}*10^{6}[/tex]

ppm= 177.97

The concentration of the resulting solution in parts per million is 177.97

A 12.00g sample of MgCl2 was dissolved in water. 0.2500mol of AgNO3 was required to precipitate all the chloride ions from the solution. Calculate the purity (as a mass percentage) of MgCl2 in the sample. Your answer should have four significant figures (round to the nearest hundredth of a percent).

Answers

Answer:

[tex]Purity=99\%[/tex]

Explanation:

Hello,

In this case, the undergoing precipitation reaction is:

[tex]MgCl_2+2AgNO_3\rightarrow Mg(NO_3)_2+2AgCl[/tex]

Thus, for the 0.2500 moles of silver nitrate, the following mass of magnesium chloride is consumed (consider their 2:1 molar ratio):

[tex]m_{MgCl_2}=0.2500molAgNO_3*\frac{1molMgCl_2}{2molAgNO_3} *\frac{95.2gMgCl_2}{1molMgCl_2} \\\\m_{MgCl_2}=11.90gMgCl_2[/tex]

Therefore, the purity of the sample is:

[tex]Purity=\frac{11.90g}{12.00g}*100\%\\ \\Purity=99\%[/tex]

Best regards.

Answer: 99. 17%

Explanation:

MgCl2(aq)+2AgNO3(aq)⟶2AgCl(s)+Mg(NO3)2(aq)

(0.2500 mol AgNO3 × 1 mol (MgCl2) /2 mol (AgNO3) × 95.211 g MgCl2 /1 mol MgCl2)

divided by 12.00 g sample = 0.99178 X 100 ≈ 99.18%

Burning a compound of calcium, carbon and nitrogen in oxygen generates calcium oxide (CaO), carbon dioxide (CO2) and nitrogen dioxide (NO2). A small sample gives 3.106 g CaO, 2.439 g CO2, and 5.097g NO2. Determine the empirical formula of the compound.

Answers

Answer:

CaCN₂

Explanation:

A compound of calcium, carbon and nitrogen CaₐCₓNₙ in oxygen will burning producing:

CaₐCₓNₙ + O₂ → aCaO + xCO₂ + nNO₂

Moles of the oxides CaO, CO₂, NO₂ are:

CaO: 3.106g ₓ (1 mole / 56.08g) = 0.0554 moles of CaO = moles of Ca

CO₂: 2.439g ₓ (1mole / 44g) = 0.0554 moles CO₂ = moles C

NO₂: 5.097g ₓ (1mole / 46g) = 0.111 moles NO₂ = moles N

Empirical formula is the chemical formula that represents the simplest ratio of elements in a compound.

Having as basis 0.0554 moles (The lower number of moles):

0.0554 moles Ca / 0.0554 = 1 Ca

0.0554 moles C / 0.0554 = 1 C

0.111 moles N / 0.0554 = 2N

Thus, the compound CaₐCₓNₙ  has as empirical formula:

Ca₁C₁N₂ = CaCN₂

Select the correct answer. What is the number of protons in this carbon atom? A. 12 B. 6 C. 18 D. 24

Answers

Answer:

The correct answer is

C. 6 Protons

Explanation:

Carbon is a nonmetallic element that is available in  both organic and inorganic compounds.

    Carbon belongs to group 14 elements in the periodic table,carbon is a chemical element with the symbol C and atomic number 6, it can  form long chains with its own atoms, a feature called catenation.

Two allotropes of carbon available are diamonds and graphites, which have different crystalline structures

The physical properties of carbon vary widely with the allotropic form.

examples are.

Graphite, diamonds and coal are all nearly pure forms of carbonDiamond is highly transparent. Graphite is opaque and blackDiamond is one of the hardest substances known to man. Graphite is soft and often used as the "lead" in lead pencilsDiamond has a very low electrical conductivity. Graphite is a very good conductorVery brittle, and cannot be rolled into wires or pounded into sheets

what is the mass of 3.50 moles of silicon dioxide

Answers

Answer:

210. g

Explanation:

SiO2 molar mass=60.09 g/mol

3.50 mol * 60.09 g/mol = 210. g

In the background information, it was stated that CaF2 has solubility, at room temperature, of 0.00160 g per 100 g of water. How many moles of CaF2 can dissolve in 100 g of water? If the density of a saturated solution of CaF2 is 1.00 g/mL, how many moles of CaF2 will dissolve in exactly 1.00 L of solution?

Answers

Answer:

2.05*10⁻⁵ moles of CF₂ can dissolve in 100 g of water.

12.82 moles of CaF₂ will dissolve in exactly 1.00 L of solution

Explanation:

First, by definition of solubility, in 100 g of water there are 0.0016 g of CaF₂. So, to know how many moles are 0.0016 g, you must know the molar mass of the compound. For that you know:

Ca: 40 g/moleF: 19 g/mole

So the molar mass of CaF₂ is:

CaF₂= 40 g/mole + 2*19 g/mole= 78 g/mole

Now you can apply the following rule of three: if there are 78 grams of CaF₂ in 1 mole, in 0.0016 grams of the compound how many moles are there?

[tex]moles=\frac{0.0016 grams*1 mole}{78 grams}[/tex]

moles=2.05*10⁻⁵

2.05*10⁻⁵ moles of CF₂ can dissolve in 100 g of water.

Now, to answer the following question, you can apply the following rule of three: if by definition of density in 1 mL there is 1 g of CaF₂, in 1000 mL (where 1L = 1000mL) how much mass of the compound is there?

[tex]mass of CaF_{2}=\frac{1000 mL*1g}{1mL}[/tex]

mass of CaF₂= 1000 g

Now you can apply the following rule of three: if there are 78 grams of CaF₂ in 1 mole, in 1000 grams of the compound how many moles are there?

[tex]moles=\frac{1000 grams*1 mole}{78 grams}[/tex]

moles=12.82

12.82 moles of CaF₂ will dissolve in exactly 1.00 L of solution

Which of the following is not a correct statement regarding the energy in a chemical bond? It is stored between atoms. It is known as bond energy. It is energy associated with motion. It has a fixed quantity.

Answers

Answer:it has fixed quantity

Explanation:energy between chemical bonds is hard to measure

Answer:

It has a fixed quantity.

Explanation:

What is the reactant(s) in the chemical equation below?
300(g) + Fe2O3(s) → 2Fe(s) + 3C02(9)
O A. 2Fe(s)
B. Fe2O3(s)
C. 2Fe(s) + 3C02(9)
D. 300(g) + Fe2O3(s)
SUBMIT

Answers

Answer:

I think it's D. 300(g) + Fe2O3(s)

Methanol is classified as what alcohol

Answers

Answer:

Hey mate,

Here is your answer. Hope it helps you

Explanation:

Primary alcohols are those alcohols where the carbon atom of the hydroxyl group(OH) is attached to only one single alkyl group. Some of the examples of these primary alcohols include Methanol (, propanol, ethanol, etc. The complexity of this alkyl chain is unrelated to the classification of any alcohol considered as primary. The existence of only one linkage among –OH group and an alkyl group and the thing that qualifies any alcohol as a primary.

How many grams of Li are there in 1.39 moles of Li?

Answers

Answer:

6.941 grams

Explanation:

The molecular formula for Lithium is Li. The Si base unit for amount of substance is mole. 1 mole is equal to 1 moles Lithium, or 6.941 grams

Answer:

9.647989999999998

Explanation:

Write the condensed structural formula of the ester formed when each Of the following reacts with methanol. For example, the ester formed when propanoic acid (CH3CH2COOH) reacts With methanol (HOCH3) is CH3CH2COOCH3.

a. acetic acid (CH3COOH)
b. butanoic acid

Answers

Answer:

1. Methyl ethanoate i.e CH3COOCH3

2. Methyl butanoate i.e CH3CH2CH2COOCH3

Explanation:

The reaction between an organic acid and alcohol is called esterification in which an ester is formed along side with water.

Thus, the name ester formed can be obtained as follow:

1. Reaction of acetic acid, CH3COOH with methanol, CH3OH.

CH3COOH + HOCH3 –> CH3COOCH3 + H2O

The name of the ester formed is methyl ethanoate i.e CH3COOCH3

2. Reaction of butanoic acid, CH3CH2CH2COOH with methanol, CH3OH.

CH3CH2CH2COOH + HOCH3 —> CH3CH2CH2COOCH3 + H2O

The name of the ester formed is methyl butanoate i.e CH3CH2CH2COOCH3

It is usually assumed that an action potential begins immediately at the cathode. If this were true, both methods for calculating conduction velocity would provide the same answer. However, when a strong stimulus intensity is used, the action potential may begin some distance away from the cathode. Under these conditions, the difference method would be more accurate.Did you observe any important difference between the conduction velocity values?

Answers

Answer: Provided in the explanation section

Explanation:

Our questions says that:

It is usually assumed that an action potential begins immediately at the cathode. If this were true, both methods for calculating conduction velocity would provide the same answer. However, when a strong stimulus intensity is used, the action potential may begin some distance away from the cathode. Under these conditions, the difference method would be more accurate.Did you observe any important difference between the conduction velocity values?

Answer to this :

By using the difference method, you subtract out any "uncertainties" involved in the measurement of latencies. Say for example, saw we are uncertain as to where the AP's are actually originating within the vicinity of the stimulating electrodes, this "error" will be introduced into both latency measurements, and therefore subtracted out when performing a difference method calculation.

However, the difference method is only experimentally sound when one is dealing with the same population of nerve fibres over the recording electrodes used, which is not the case with the sciatic nerve, as it is a short nerve, and thin at one end.

    The non-uniformity of the nerve, and the difficulty in making accurate measurements of very small distances and latencies are principal points to consider when making conduction velocity measurements. Naturally if the nerve studied were longer and more uniform, we would improve the accuracy of our calculations.

cheers i hope this helped !!!!

PCl5 dissociates according to the reaction: PCl5(g) = PCl3(g) + Cl2(g) One mole of PCl5 was placed in one liter of solution. When equilibrium was established, 0.2 mole of PCl5 remained in the mixture. What is the equilibrium constant for this reaction? (Hint: remember the ICE procedure? initial, change, and equilibrium)

Answers

Answer:

[tex]K=3.2[/tex]

Explanation:

Hello,

In this case, for the given equilibrium, we write the law of mass action:

[tex]K=\frac{[PCl_3][Cl_2]}{[PCl_5]}[/tex]

Next, in terms of the change [tex]x[/tex] due to the reaction extent (ICE procedure):

[tex]K=\frac{x*x}{1M-x}[/tex]

Clearly, the initial concentration phosphorous pentachloride is 1 M (one mole per litre), therefore, since the equilibrium concentration is 0.2 M (same volume) we can compute [tex]x[/tex]:

[tex]x=1M-0.2M=0.8M[/tex]

Thus, we compute the equilibrium constant:

[tex]K=\frac{0.8*0.8}{0.2} \\\\K=3.2[/tex]

Regards.

Why would it be important to use a homogeneous mixture instead of a heterogeneous mixture for a
specific application?
A homogeneous mixture has different properties throughout, but this would not
affect the use of a material for a specific application.
A homogeneous mixture has the same properties for every part of the mixture, so
the quality of the material is consistent.
A homogeneous mixture has the same appearance throughout, even if it has
different properties.
A homogeneous mixture has all of the required components, and this is the most
important part of using a material for a specific application.

Answers

The correct answer is B. A homogeneous mixture has the same properties for every part of the mixture, so the quality of the material is consistent.

Explanation:

In a homogenous mixture, all the components are equally integrated; this means the final result in the case of a material is a material that looks uniform and also has the same properties in every part of section. This homogeneity and consistency are especially important if you are testing the properties of the material or using it for a specific application because if you use a homogenous mixture the quality and properties will be consistent and thus you can obtain consistent results.

Element M reacts with oxygen to form an oxide with the formula MO. When MO is dissolved in water, the resulting solution is basic. Element M could be ________.Element M reacts with oxygen to form an oxide with the formula MO. When MO is dissolved in water, the resulting solution is basic. Element M could be ________.arsenicgermaniumchlorinecalciumselenium

Answers

Answer:

Calcium

Explanation:

Since the element reacts with oxygen to form an oxide with the formula MO, the charge on the element is +2.

Also, since the oxide MO when dissolved in water is basic, the metal is an alkali earth metal.

From the above conditions;

The metal is not arsenic because arsenic is a metalloid has the  following oxides As₂O₃ and As₃O₅ and are respectively amphoteric and acidic in nature

The metal is not germanium because is a metalloid and even though germanium oxide has the formula GeO₂, it is amphoteric.

The metal is not chlorine because chlorine is a non-metal

The metal is definitely calcium because calcium oxide has the formula CaO and calcium is an alkaline earth metal.

The metal is not selenium because selenium is anon-meal and its oxide has the formula Se0₂ and is acidic

An aluminum can weighing 10 g absorbs 106.8 J of heat and warms by 12oC. What is the specific heat of the aluminum can?

Answers

Answer:

THE SPECIFIC HEAT CAPACITY OF THE ALUMINIUM CAN IS 0.03747 J/g K

Explanation:

Heat liberated (Q) = MCΔT

Heat = 106.8 J

M = mass = 10 g

ΔT = 12°C= 12 + 273 K = 285 K

C = specific heat capacity = unknown

At a rise in 12 °C temperature, the aluminium can possesses a specific heat capacity of =

C = Q / MΔT

C = 106.8 J / 10 g * 285 K

C = 106.8 J / 2850 g K

C = 0.03747 J/g K

The specific heat capacity of the aluminum can weighing 10 g and absorbs 106.8 J of heat after been warmed to 12°C is 0.03747 J/ g K

Answer:

The specific heat of the aluminium can is 0.89 J/g°C

Explanation:

Step 1: Data given

Mass of the aluminium can = 10.0 grams

The amount of energy absorbed = 106.8 J

The temperature rises 12.0 °C

Step 2: Calculate the specific heat of the aluminium can

Q = m*c* ΔT

⇒with Q = the heat absorbed = 106.8 J

⇒with m = the mass of the aluminium can = 10.0 grams

⇒with c = the specific heat of the aluminium can = TO BE DETERMINED

⇒with ΔT = the rise of the temperature = 1.0°C

106.8 J = 10.0 grams * C * 12.0 °C

C = 106.8 J / (10.0 grams * 12.0 °C)

C = 0.89 J/g°C

The specific heat of the aluminium can is 0.89 J/g°C

A metal ion with a net +1 charge has ten electrons in the 3d subshell. How do I identify the metal?

Answers

Explanation:

First off, the + 1 charge means that the metal has lost an electron.

To identify the metal, we have to know the total number of electrons in the 3d sub shell.

Total number of electrons = 1 + 10 = 11

This metal belongs to the fourth period in the periodic table (that's where transition metals begin to occur).

This means that the 11th metal in this period is the metal. That happends to be Copper.

What is the scientific explanation of boiling point elevation?

Answers

Explanation:

Boiling-point elevation describes the phenomenon that the boiling point of a liquid (a solvent) will be higher when another compound is added, meaning that a solution has a higher boiling point than a pure solvent. This happens whenever a non-volatile solute, such as a salt, is added to a pure solvent, such as water.

Hope it was helpful

3. The following data of decomposition reaction of thionyl chloride (SO2Cl2) were collected at a certain temperature and the concentration of SO2Cl2 were monitored as shown in the table.

SO2Cl2 (g) SO2 (g) + Cl2 (g)



Time (min) Conc. of SO2Cl2 (mol/L)

0 0.1000

100 0.0876

200 0.0768

300 0.0673

400 0.0590

500 0.0517

600 0.0453

700 0.0397

800 0.0348

900 0.0305

1000 0.0267

1100 0.0234



a) Determine graphically whether the kinetics of the reaction is zero order, first order or second order with respect to SO2Cl2 and then write the rate equation.

b) Determine the rate constant (k) of the reaction.

c) Determine the half-life (t½) for the reaction.

d) What will be the concentration of SO2Cl2 left in the reaction mixture at 1500 minutes?

Answers

Answer:

a) First-order.

b) 0.013 min⁻¹

c) 53.3 min.

d) 0.0142M

Explanation:

Hello,

In this case, on the attached document, we can notice the corresponding plot for each possible order of reaction. Thus, we should remember that in zeroth-order we plot the concentration of the reactant (SO2Cl2 ) versus the time, in first-order the natural logarithm of the concentration of the reactant (SO2Cl2 ) versus the time and in second-order reactions the inverse of the concentration of the reactant (SO2Cl2 ) versus the time.

a) In such a way, we realize the best fit is exhibited by the first-order model which shows a straight line (R=1) which has a slope of -0.0013 and an intercept of -2.3025 (natural logarithm of 0.1 which corresponds to the initial concentration). Therefore, the reaction has a first-order kinetics.

b) Since the slope is -0.0013 (take two random values), the rate constant is 0.013 min⁻¹:

[tex]m=\frac{ln(0.0768)-ln(0.0876)}{200min-100min} =-0.0013min^{-1}[/tex]

c) Half life for first-order kinetics is computed by:

[tex]t_{1/2}=\frac{ln(2)}{k}=\frac{ln(2)}{0.013min^{-1}} =53.3min[/tex]

d) Here, we compute the concentration via the integrated rate law once 1500 minutes have passed:

[tex]C=C_0exp(-kt)=0.1Mexp(-0.013min^{-1}*1500min)\\\\C=0.0142M[/tex]

Best regards.

A water molecule consists of an oxygen atom and two hydrogen atoms covalently bonded in a bent shape. Oxygen however, attracts the shared electrons more strongly than the hydrogen atoms. This structure leads to which important property of water?a. Water is non-polar, which means it has an uneven distribution of charge making it a good solvent of other non-polar molecules.b. Water is non-polar, which means it an an even distribution of charge making it a good solvent of polar molecules.c. Water is polar, which means it has an even distribution of charge making it a good solvent of non-polar molecules.d. Water is polar, which means it has an uneven distribution of charge making it a good solvent of other polar molecules.

Answers

Answer:

D.

Explanation:

Water is polar, for one thing. Polar mixes with polar, nonpolar mixes wih nonpolar. This leaves D.

Why does reducing solute particle size increase the speed at which the solute

dissolves in water?

A. It makes the temperature of the water significantly higher.

B. It exposes morg of the solute to the water molecules.

C. It makes the water molecules move around faster.

O

D. It raises the pressure of the water molecules on the solute.

Answers

Answer: B. It exposes more of the solute to the water molecules.

Explanation:

Rate of a reaction is dependent on following factors:

a) adding a catalyst: Adding a catalyst increases the rate of reaction

b) reducing the surface area: The rate of the reaction will decrease by reducing the surface area

c) raising the temperature: Increasing the temperature increases the rate of the reaction.

d) increasing the amount of reactants : Increasing the amount of reactants increases the rate of reaction.

If the reactants are present in smaller size, more reactants can react as decreasing the size increases the surface area of the reactants which will enhance the contact of molecules. Hence, more products will form leading to increased rate of reaction.

Thus reducing solute particle size increase the speed at which the solute dissolves in water by exposing more of the solute to the water molecules.

Answer:

B. It exposes more of the solute to the water molecules.

Select all the true statements. Group of answer choices The +3 oxidation state is characteristic of the actinides. All actinides are radioactive. Cerium (Ce) rnakes 100th in abundance (by mass %). Valence-state electronegativity is when a metal with a positive oxidation state has a greater attraction for the bonded electrons (thus a higher electronegativity) than it does when it has a 0 oxidation state. The actinides are silvery and chemically reactive. The lanthanides are in Period 7.

Answers

Answer:

The +3 oxidation state is characteristic of the actinides.

All actinides are radioactive.

Cerium (Ce) rnakes 100th in abundance (by mass %).

The actinides are silvery and chemically reactive.

In the periodic table,the The +3 oxidation state is characteristic of the actinides. All actinides are radioactive.The actinides are silvery and chemically reactive.

What is periodic table?

Periodic table is a tabular arrangement of elements in the form of a table. In the periodic table, elements are arranged according to the modern periodic law which states that the properties of elements are a periodic function of their atomic numbers.

It is called as periodic because properties repeat after regular intervals of atomic numbers . It is a tabular arrangement consisting of seven horizontal rows called periods and eighteen vertical columns called groups.

Elements present in the same group have same number of valence electrons and hence have similar properties while elements present in the same period show gradual variation in properties due to addition of one electron for each successive element in a period.

Learn more about periodic table,here:

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Methanol CH3OH is the simplest of the alcohols . It is sinthesized by the reaction of hydrogen and carbon monoxide.

CO + H2 -----------> CH3OH

a) If 500 ml CO and 750 mol H2 are present, which is the limiting reactant?

b) How many mols of excess reactant remain unchange?

c) How many moles of CH3OH are formed ?

Answers

Answer:

a) CO is the limiting reactant.

b) [tex]n_{H_2}^{excess}=749.9592molH_2[/tex]

c) [tex]n_{CH_3OH}=0.0204molCH_3OH[/tex]

Explanation:

Hello,

In this case, the balanced chemical reaction:

[tex]CO + 2H_2 \rightarrow CH_3OH[/tex]

So we proceed as follows:

a) We first compute the moles of CO by using its density (0.00114 g/mL) and molar mass (28 g/mol):

[tex]n_{CO}=500mLCO*\frac{0.00114gCO}{1mLCO}*\frac{1molCO}{28gCO}=0.0204molCO[/tex]

Next, with the given 750 moles of hydrogen, we can compute the moles of carbon monoxide that are consumed by such amount of hydrogen by using their 1:2 molar ratio:

[tex]n_{CO}^{consumed\ by\ H_2}=750molH_2*\frac{1molCO}{2molH_2}=375molCO[/tex]

Thus, we see a clear excess of hydrogen, for that reason the carbon monoxide is the limiting reactant.

b) In this case, we first compute the moles of CO that are not consumed:

[tex]n_{CO}^{unchanged}=375mol-0.0204mol=374.9796molCO[/tex]

Next, we use the 1:2 molar ratio again to compute the unchanged moles of hydrogen which is the excess reactant:

[tex]n_{H_2}^{excess}=375.9796molCO*\frac{2molH_2}{1molCO} =749.9592molH_2[/tex]

c) Finally, we use the reacting moles of carbon monoxide to compute the formed moles of methanol by using the 1:1 molar ratio:

[tex]n_{CH_3OH}=0.0204molCO*\frac{1molCH_3OH}{1molCO} =0.0204molCH_3OH[/tex]

Best regards.

Consider the titration of 1.0 L of 1.0 M NH3 with 1.0 M HCl. Which of the following correctly describe(s) how the pH would be calculated at each of the following additions of HCl? I: At 0 L HCl, pH would be calculated based on the concentration and Kb of the weak base II: At 1 L HCl, pH would be calculated based on the concentration and Ka of the conjugate acid III: At 2 L HCl, pH would be calculated based on the concentration of excess acid in solution Group of answer choices I and III Only II Only I I, II, and III II and III

Answers

Answer:

I, II, and III

Explanation:

In the titration of NH₃ with HCl:

NH₃ + HCl → NH₄⁺ + Cl⁻

Where NH₃ is the weak base and NH₄⁺ is the conjugate acid.

I: At 0 L HCl, pH would be calculated based on the concentration and Kb of the weak base: At 0L of HCl, you will have just NH₃ in solution. That means you would calculate the pH just from the concentration of the weak base using Kb. That means I is true.

II: At 1 L HCl, pH would be calculated based on the concentration and Ka of the conjugate acid: When you add 1L of HCl, you will have in solution just NH₄⁺, the conjugate acid. That means you would calculate the pH of the solution just with the Ka of the conjugate acid and its concentration. II is true.

III: At 2 L HCl, pH would be calculated based on the concentration of excess acid in solution: At 2L of HCl solution, you have HCl in excess in the solution. As HCl is a strong acid, the pH would be affected in the big way by this concentration in excess. III is true.

what's the answer to this question

Answers

Answer:

D

Explanation:

From given choices it is D.

How many moles of an ideal gas are in a tank with a volume of 22.9 L at pressure of 14.297 atm at 12°C? ( Show work and units )

Answers

Answer:

14 moles

Explanation:

For an Ideal gas,

PV = nRT...................... Equation 1

Where P = Pressure, V = Volume, n = number of mole, R = Molar gas constant.

make n the subject of the equation

n = PV/RT.................. Equation 2

Given: P = 14.297 atm, V = 22.9 L = 22.9 dm³, T = 12 °C = (12+273) K = 285 K.

Constant: R = 0.082 atm.dm³/K.mol

Substitute these values into equation 2

n = (14.297×22.9)/(285×0.082)

n = 327.4013/23.37

n = 14.009

n ≈ 14 moles

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